Author(s): Liu, CZ (Liu, Chaozhong); Niu, CY (Niu, Chunyao); Gao, B (Gao, Bo); Jiang, PL (Jiang, Pingli); Lin, QY (Lin, Qiyao); Wu, WZ (Wu, Wenzhuo); Jia, Y (Jia, Yu); Wei, ZM (Wei, Zhongming); Xu, Q (Xu, Qun)

Source: CHEMNANOMAT DOI: 10.1002/cnma.202300195  Early Access Date: JUN 2023  

Abstract: The construction of suitable metal/substrate interfaces that can synergistically optimize the water dissociation, hydrogen transfer and hydrogen adsorption processes has proved to be a promising approach to boost the alkaline electrochemical hydrogen evolution reaction (HER) but remains challenging. Herein, a Pt/GaN heterostructure electrocatalyst is constructed using the electrochemical deposition technique and used for alkaline electrochemical HER. The as-synthesized Pt/GaN catalyst exhibits competitive HER performance, including low overpotentials of 24 and 441 mV to reach current densities of 10 and 1000 mA cm(-2), respectively, and a superior mass activity (7.34 A mg(Pt)(-1) at the overpotential of 100 mV), which is 25.7 and 5.0 times higher than commercial Pt/C and as-synthesized Pt/CP, respectively. First-principle calculations suggest that the Pt/GaN heterostructure can greatly reduce the energy barrier for H2O dissociation, create a local acid-like microenvironment through a H spillover process and optimize the value of & UDelta;G(H), leading to a remarkable acceleration of the alkaline HER kinetics. This discovery provides new insights for the development of alkaline HER catalysts.

Accession Number: WOS:001016530500001

ISSN: 2199-692X