A Model of Dual Fabry-Perot Etalon-Based External-Cavity Tunable Laser Us...
Internal motion within pulsating pure-quartic soliton molecules in a fibe...
Enhanced light emission of germanium light-emitting-diode on 150 mm germa...
The Fabrication of GaN Nanostructures Using Cost-Effective Methods for Ap...
Negative-to-Positive Tunnel Magnetoresistance in van der Waals Fe3GeTe2/C...
Quantum Light Source Based on Semiconductor Quantum Dots: A Review
A High-Reliability RF MEMS Metal-Contact Switch Based on Al-Sc Alloy
Development of a Mode-Locked Fiber Laser Utilizing a Niobium Diselenide S...
Development of Multiple Fano-Resonance-Based All-Dielectric Metastructure...
Traffic Vibration Signal Analysis of DAS Fiber Optic Cables with Differen...
官方微信
友情链接

Preparation of polymeric carbon nitride/TiO2 heterostructure with NH4Cl as template: Structural and photocatalytic studies

2022-04-29

 

Author(s): Wu, ZJ (Wu, Zhengjie); Zhao, YH (Zhao, Youhai); Chen, X (Chen, Xiong); Guo, YX (Guo, Yongxiang); Wang, HW (Wang, Haiwang); Jin, YR (Jin, Yaran); He, P (He, Ping); Wei, QQ (Wei, Qingquan); Wang, BZ (Wang, Bingzhu)

Source: JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS Volume: 164 Article Number: 110629 DOI: 10.1016/j.jpcs.2022.110629 Published: MAY 2022

Abstract: In this paper, a method for preparing polymeric carbon nitride/TiO2 (PCN/TiO2) with NH4Cl as template is proposed. Comparing with PCN prepared with conventional methods, the specific surface area of PCN/TiO2 is higher, which also improves the photocatalytic performance. The structure and evolution of samples were explored via FT-IR, XRD, SEM, TEM, BET and XPS in order to analyze the reaction mechanism of PCN/TiO2. In the meantime, the electron-hole separation efficiency and energy band structure were explored by PL and UV-Vis spectra. In addition, the RhB degradation mechanism and electrons-holes transport path of PCN/TiO(2 )was analyzed by degradation experiments and EPR. The results show that the NH4Cl which is the template was decomposed after calcination, therefore PCN showed the porous morphology. The compound of PCN and TiO2 formed heterojunction, which can effectively promote the electron-hole separation rate to improve the photo catalytic efficiency. The PCN/TiO2(2.5:1) was found to have the best dye degradation efficiency and the degradation rate of RhB could reach 83.81% within 150 min. During the degradation of RhB, the active substances are h+, center dot & nbsp;OH and center dot & nbsp;O-2(-) and the mechanism of electron-hole transmission is Type-Z transport mechanism.

Accession Number: WOS:000777830500002

ISSN: 0022-3697

eISSN: 1879-2553

Full Text: https://www.sciencedirect.com/science/article/pii/S0022369722000579?via%3Dihub



关于我们
下载视频观看
联系方式
通信地址

北京市海淀区清华东路甲35号(林大北路中段) 北京912信箱 (100083)

电话

010-82304210/010-82305052(传真)

E-mail

semi@semi.ac.cn

交通地图
版权所有 中国科学院半导体研究所

备案号:京ICP备05085259-1号 京公网安备110402500052 中国科学院半导体所声明