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Origin of hydrogen passivation in 4H-SiC

2021-07-09

 

Author(s): Cai, XF (Cai, Xuefen); Yang, Y (Yang, Yang); Deng, HX (Deng, Hui-Xiong); Wei, SH (Wei, Su-Huai)

Source: PHYSICAL REVIEW MATERIALS Volume: 5 Issue: 6 Article Number: 064604 DOI: 10.1103/PhysRevMaterials.5.064604 Published: JUN 22 2021

Abstract: Carbon vacancy VC is the dominant detrimental defect in SiC, and hydrogen passivation of V-C is often used to facilitate its application in electronic devices. However, the exact nature of hydrogen passivation of V-C in 4H-SiC remains inconclusive in view of the available divergent experiment and theoretical findings. Here, using the Heyd-Scuseria-Ernzerhof screened hybrid density functional calculations, we demonstrate that the V-C defect can capture up to four hydrogens, and the electrically active levels within the band gap can be entirely passivated, in line with recent reported experimental observations. This paper, thus, casts light on the role of hydrogen passivation in SiC.

Accession Number: WOS:000664650400003

ISSN: 2475-9953

Full Text: https://journals.aps.org/prmaterials/abstract/10.1103/PhysRevMaterials.5.064604



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